DEHiBA, D2EHIBA
N,N-dialkylamide
C20H41NO CHON
311.546 g/mol
U, [Tc(VII), Np(VI)]
France
France
Factor | Value | Conc. | Add. ligand | Aq. acid | Organic diluent | Temp. | Contact time | Additional | Ref. |
---|---|---|---|---|---|---|---|---|---|
U/Th | 370 | 1 M | HNO3 4 M | n-Dodecane | 25°C | [1] | |||
U/Th | 3000 | 0.18 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [1] | ||
U/Th | 1670 | 0.5 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [1] | ||
U/Th | 220 | 1 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [1] | ||
U(VI)/Pu(IV) | ≈80 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 10 min | calculated in the SoA Report (soar-7267) | [2] | |
U/Zr | 134 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Zr | 793 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Zr | 1247 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Zr | 131 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Zr | 59 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Zr | 44 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Th | 120 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Th | 343 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Th | 315 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Th | 370 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Th | 230 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | [3] | ||
U/Th | 110 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | [3] |
Element | Value | Conc. | Add. ligand | Aq. acid | Organic diluent | Temp. | Contact time | Additional | Ref. |
---|---|---|---|---|---|---|---|---|---|
U | 1.95 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 2 min | [3] | ||
U | 2.01 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 5 min | [3] | ||
U | 2.13 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 15 min | [3] | ||
U | 2.22 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 30 min | [3] | ||
U | 2.16 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 60 min | [3] | ||
U | 2.24 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 125 min | [3] | ||
U | 3.77 | 1 M | HNO3 6 M | n-Dodecane | 25°C | 2 min | [3] | ||
U | 4.08 | 1 M | HNO3 6 M | n-Dodecane | 25°C | 5 min | [3] | ||
U | 4.01 | 1 M | HNO3 6 M | n-Dodecane | 25°C | 15 min | [3] | ||
U | 4.18 | 1 M | HNO3 6 M | n-Dodecane | 25°C | 30 min | [3] | ||
U | 4.18 | 1 M | HNO3 6 M | n-Dodecane | 25°C | 60 min | [3] | ||
U | 4.21 | 1 M | HNO3 6 M | n-Dodecane | 25°C | 125 min | [3] | ||
U | 0.24 | 0.88 M | HNO3 1 M | n-Dodecane | 25°C | 30 min | Tracer U amounts | [3] | |
U | 1.19 | 0.65 M | HNO3 2 M | n-Dodecane | 25°C | 30 min | Tracer U amounts | [3] | |
U | 2.37 | 0.47 M | HNO3 3 M | n-Dodecane | 25°C | 30 min | Tracer U amounts | [3] | |
U | 3.69 | 0.35 M | HNO3 4 M | n-Dodecane | 25°C | 30 min | Tracer U amounts | [3] | |
U | 4.6 | 0.26 M | HNO3 5 M | n-Dodecane | 25°C | 30 min | Tracer U amounts | [3] | |
U | 0.22 | 0.88 M | HNO3 1 M | n-Dodecane | 25°C | 30 min | 1g/L U | [3] | |
U | 0.96 | 0.65 M | HNO3 2 M | n-Dodecane | 25°C | 30 min | 1g/L U | [3] | |
U | 2.08 | 0.47 M | HNO3 3 M | n-Dodecane | 25°C | 30 min | 1g/L U | [3] | |
U | 3.17 | 0.35 M | HNO3 4 M | n-Dodecane | 25°C | 30 min | 1g/L U | [3] | |
U | 3.63 | 0.26 M | HNO3 5 M | n-Dodecane | 25°C | 30 min | 1g/L U | [3] | |
Ce | 25000 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 58000 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 52000 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 60000 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 30000 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 51000 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 55000 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 50000 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | <1 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 6 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 450 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 480 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 580 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 480 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 370 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Zr | 250 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 19000 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 12000 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 21000 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 10000 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 28000 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 36000 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 77000 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Eu | 71000 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 1800 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 2100 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 1100 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 1300 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 4700 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 1300 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 9200 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Fe | 9200 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 2300 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 3000 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 2400 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 2400 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 2100 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 2700 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 3000 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Cs | 1400 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Ce | 40000 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 30000 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 29000 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 72000 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 43000 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 61000 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 52000 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Ce | 31000 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Ce amounts | [3] | |
Zr | 10000 | 1 M | HNO3 0.1 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Zr | 1800 | 1 M | HNO3 1.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Zr | 1500 | 1 M | HNO3 2.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Zr | 1900 | 1 M | HNO3 3.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Zr | 28000 | 1 M | HNO3 4.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Zr | 78000 | 1 M | HNO3 5.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Zr | 100000 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th; Tracer Zr amounts | [3] | |
Th | 0.0015 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | Tracer Th amounts | [3] | |
Th | 0.04 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | Tracer Th amounts | [3] | |
Th | 0.0045 | 1 M | HNO3 0.01 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
Th | 0.037 | 1 M | HNO3 6.0 M | n-Dodecane | 25°C | 30 min | 250g/L Th | [3] | |
U | 1.2 | 0.18 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [3] | ||
U | 4 | 0.5 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [3] | ||
U | 6 | 1 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [3] | ||
Th | 0.0004 | 0.18 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [3] | ||
Th | 0.0024 | 0.5 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [3] | ||
Th | 0.027 | 1 M | HNO3 4 M | n-Dodecane | 25°C | 200 g/L Th | [3] | ||
U | 3.7 | 1 M | HNO3 4 M | n-Dodecane | 25°C | [3] | |||
Th | 0.01 | 1 M | HNO3 4 M | n-Dodecane | 25°C | [3] | |||
U(VI) | 2.73 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 10 min | [3] | ||
Np(VI) | 1.23 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 10 min | [3] | ||
Pu(IV) | 0.034 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 10 min | [3] | ||
Np(IV) | <0.01 | 1 M | HNO3 3 M | n-Dodecane | 25°C | 10 min | [3] | ||
Am(VI) | ≈0.01 | 1 M | HNO3 2 M | n-Dodecane | 23°C | 10 s | [4] | ||
Am(VI) | ≈0.15 | 1 M | HNO3 3 M | n-Dodecane | 23°C | 10 s | [4] | ||
Am(VI) | ≈0.4 | 1 M | HNO3 4 M | n-Dodecane | 23°C | 10 s | [4] | ||
Am(VI) | ≈1 | 1 M | HNO3 5 M | n-Dodecane | 23°C | 10 s | [4] | ||
Am(VI) | ≈2 | 1 M | HNO3 6 M | n-Dodecane | 23°C | 10 s | [4] | ||
Am(VI) | ≈2 | 1 M | HNO3 7 M | n-Dodecane | 23°C | 10 s | [4] | ||
U(VI) | ≈3.3 | 1 M | HNO3 4 M | n-Dodecane | 23°C | 10 s | [4] | ||
U(VI) | ≈4.3 | 1 M | HNO3 5 M | n-Dodecane | 23°C | 10 s | [4] | ||
U(VI) | ≈4.1 | 1 M | HNO3 6 M | n-Dodecane | 23°C | 10 s | [4] | ||
U(VI) | ≈4 | 1 M | HNO3 7 M | n-Dodecane | 23°C | 10 s | [4] | ||
Np(VI) | ≈2.6 | 1 M | HNO3 4 M | n-Dodecane | 23°C | 10 s | [4] | ||
Np(VI) | ≈3.5 | 1 M | HNO3 5 M | n-Dodecane | 23°C | 10 s | [4] | ||
Np(VI) | ≈3.8 | 1 M | HNO3 6 M | n-Dodecane | 23°C | 10 s | [4] | ||
Np(VI) | ≈3.9 | 1 M | HNO3 7 M | n-Dodecane | 23°C | 10 s | [4] | ||
Pu(IV) | ≈0.85 | 1 M | HNO3 4 M | n-Dodecane | 23°C | 10 s | [4] | ||
Pu(IV) | ≈1.2 | 1 M | HNO3 5 M | n-Dodecane | 23°C | 10 s | [4] | ||
Pu(IV) | ≈1.8 | 1 M | HNO3 6 M | n-Dodecane | 23°C | 10 s | [4] | ||
Pu(IV) | ≈2.1 | 1 M | HNO3 7 M | n-Dodecane | 23°C | 10 s | [4] | ||
Ce(IV) | ≈0.36 | 1 M | HNO3 2 M | n-Dodecane | 23°C | 10 s | [4] | ||
Ce(IV) | ≈0.9 | 1 M | HNO3 3 M | n-Dodecane | 23°C | 10 s | [4] | ||
Ce(IV) | ≈1.5 | 1 M | HNO3 4 M | n-Dodecane | 23°C | 10 s | [4] | ||
Ce(IV) | ≈1.6 | 1 M | HNO3 5 M | n-Dodecane | 23°C | 10 s | [4] | ||
Ce(IV) | ≈1.5 | 1 M | HNO3 6 M | n-Dodecane | 23°C | 10 s | [4] | ||
Ce(IV) | ≈1 | 1 M | HNO3 7 M | n-Dodecane | 23°C | 10 s | [4] |
Element | Value | Conc. | Add. ligand | Aq. acid | Organic diluent | Temp. | Additional | Stages | Ref. |
---|---|---|---|---|---|---|---|---|---|
Th | 1200 | 0.5 M | TBP 5 % | HNO3 4 M | n-dodecane | THOREX feed solution | 12 | [5] | |
Np | >300 | 1 M | HNO3 6 M | hydrogenated tetrapropylene | 70 GWd/t; 6 years of cooling; hot tests | 12 | [6] | ||
Pu | 4100 | 1 M | HNO3 6 M | hydrogenated tetrapropylene | 70 GWd/t; 6 years of cooling; hot tests | 12 | [6] | ||
Tc | 41 | 1 M | HNO3 6 M | hydrogenated tetrapropylene | 70 GWd/t; 6 years of cooling; hot tests | 12 | [6] | ||
Ru106 | >15000 | 1 M | HNO3 6 M | hydrogenated tetrapropylene | 70 GWd/t; 6 years of cooling; hot tests | 12 | [6] | ||
Cs137 | >35000 | 1 M | HNO3 6 M | hydrogenated tetrapropylene | 70 GWd/t; 6 years of cooling; hot tests | 12 | [6] |
Test carried out | Test type | Conditions | Ref. |
---|---|---|---|
HLW hot test, 28 mixer settlers, lab scale | [7] |
doi:10.1016/j.seppur.2003.09.005
https://inis.iaea.org/collection/NCLCollectionStore/_Public/36/010/36010983.pdf
doi:10.1081/SS-100100793
doi:10.1021/acs.iecr.7b01181
10.1016/j.seppur.2003.09.005
https://www.researchgate.net/publication/285969277_HA_demonstration
https://www.researchgate.net/publication/285969277_HA_demonstration_in_the_Atalante_facility_of_the_Ganex_1st_cycle_for_the_selective_extraction_uranium_from_HLW
CEA