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The objective of the symposium "From Thermodynamics to the Safety Case", organised jointly by the NEA TDB and Sorption Projects, was to present and discuss the principal outcomes of these two projects with interested communities (academic institutions, technical support organisations, waste management organisations, regulatory bodies). Emphasis was placed on illustrating and discussing key challenges when applying thermodynamic models and underlying databases to problems of interest for the waste management community as a whole. These proceedings contain extended abstracts of the presentations delivered by the speakers and summary records of the discussions, as well as the main conclusions and recommendations for the future work under the TDB and Sorption Projects.